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热处理制度对RCS系着色微晶玻璃析晶性能的影响

李宏 武艳萍 陈方祎 程金树

硅酸盐学报2011,Vol.39Issue(1):143-146,4.
硅酸盐学报2011,Vol.39Issue(1):143-146,4.

热处理制度对RCS系着色微晶玻璃析晶性能的影响

Influence of Heat Treatment on Crystallization Properties of Colored RcS Glass-Ceramics

李宏 1武艳萍 1陈方祎 1程金树1

作者信息

  • 1. 武汉理工大学,硅酸盐材料工程教育部重点实验室,武汉,430070
  • 折叠

摘要

Abstract

The colored R2O-CaO-SiO2 (RCS, R = Na, K) glass-ceramics were prepared through different heat treatment schedules.The influence of heat treatment on crystallization properties of the colored RCS glass-ceramics was investigated by X-ray diffraction,field emission scanning electron microscopy and UV-Visible spectrophotometer. The results indicate that the main crystalline phase of the glass-ceramics is colunnar xonotlite [Ca6Si6O17 (OH)2] at 700 ℃, and radial canasite (K2Na4Ca5Si12O3OF4) and frankamenite [K3Na3Ca5Si12O3OF3 (OH)1H2O] at 750 and 800 ℃. The color of the glass-ceramics changed from yellow to red and the cut-offwavelength shifted to a longer wavelength with the increase of heat treatment temperature and holding time.

关键词

R2O-CaO-SiO2/着色微晶玻璃/析晶性能/热处理/硫硒化镉

Key words

R2O-CaO-SiO2/ colored glass-ceramics/ crystallization properties/ heat-treatment/ sulfoselenide cadmium

分类

化学化工

引用本文复制引用

李宏,武艳萍,陈方祎,程金树..热处理制度对RCS系着色微晶玻璃析晶性能的影响[J].硅酸盐学报,2011,39(1):143-146,4.

基金项目

国家自然科学基金(50472039)及湖北省自然科学基金(2005-ABA011)资助项目. (50472039)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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