物理化学学报2011，Vol.27Issue(1)：91-96,6.
氮掺杂无定形碳负载Pd催化剂对甲醇的电催化氧化
N-Doped Amorphous Carbon Supported Pd Catalysts for Methanol Electrocatalytic Oxidation
摘要
Abstract
We prepared a new kind of N-doped amorphous carbon (CxN) by the calcination of poly-o-toluidine (POT) at 800 ℃.The prepared CxN consisted of about 8.5％ (w) nitrogen.Pd nanoparticles were deposited on CxN because of the inherent chemical activity arising from nitrogen incorporation.The Pd/CxN composite catalyst has a large electrochemically active surface area and it shows good electrocatalytic performance and stability toward methanol oxidation in alkaline media.All the results suggest that CxN can potentially find application in fuel cells.关键词
碱性直接甲醇燃料电池/聚邻甲基苯胺/煅烧/氮掺杂无定形碳/钯纳米粒子分类
化学化工引用本文复制引用
赵彦春,占璐,田建袅,聂素连,宁珍..氮掺杂无定形碳负载Pd催化剂对甲醇的电催化氧化[J].物理化学学报,2011,27(1):91-96,6.基金项目
广西自然科学基金创新团队项目(2010GXNSFF013001,0728043)和广西教育厅科研项目(桂教科研[2006]26号)资助 （2010GXNSFF013001,0728043）
