高等学校化学学报2011，Vol.32Issue(3)：538-544,7.
含吡啶鎓阳离子的氮杂环卡宾Pd(Ⅱ)配合物的合成、结构及催化性能
Synthesis, Structures and Catalytic Properties of Palladium (Ⅱ) Complexes Containing N-Heterocyclic Carbenes with Pyridinium Groups
摘要
Abstract
Four air stable palladium ( Ⅱ ) triiodine complexes containing N-heterocyclic carbenes with pyridinium groups [ (NHC)PdI3 ] have been synthesized and characterized by NMR and elemental analyses. The molecular structures of the two complexes have been confirmed by single-crystal X-ray diffraction. These NHC-Pd( Ⅱ ) complexes are active catalysts for the Suzuki-Miyanra cross-coupling reactions under atmosphere conditions with moderate conversion.关键词
氮杂环卡宾/钯/催化/Suzuki-Miyaura偶联Key words
N-Heterocyclic carbene/ Palladium/ Catalysis/ Suzuki-Miyaura coupling分类
化学化工引用本文复制引用
许卫锋,李一志,陈学太,薛子陵..含吡啶鎓阳离子的氮杂环卡宾Pd(Ⅱ)配合物的合成、结构及催化性能[J].高等学校化学学报,2011,32(3):538-544,7.基金项目
国家"九七三"计划项目(批准号:2007CB925102)和美国国家科学基金(批准号:CHE-1012173)资助. （批准号:2007CB925102）
