火炸药学报2011，Vol.34Issue(1)：25-27,3.
N2O5硝解三丙酰基三氮杂环己烷制备RDX
Preparation of RDX by Nitrolysis of 1,3,5-Tripropionyl-triazaine with N2O5
钱华 1叶志文 1谢智勇 1刘大斌1
作者信息
- 1. 南京理工大学化工学院,江苏,南京,210094
- 折叠
摘要
Abstract
A new method for the synthesis of RDX was studied with 1,3,5-tripropionyl-triazaine as raw material and N2O5/HNO3 as nitrating agent. Many factors such as the concentration of nitrating agent, ratio of reactant, reaction temperature and time were investigated. Results showed that under the molar ratio of N2O5 and HNO3 1:10, the molar ratio of N2O5 and 1,3,5-tripropionyl-triazaine 6:1, reaction temperature 45℃ and reaction time 1 h, the yield of the RDX was up to 92.7 ％ with 98.5 % purity.关键词
有机化学/N2O5/三丙酰基三氮杂环己烷/RDX/硝解/炸药Key words
organic chemistry/N2O5 /1,3,5-tripropionyl-triazaine/RDX/nitrolysis/explosive分类
军事科技引用本文复制引用
钱华,叶志文,谢智勇,刘大斌..N2O5硝解三丙酰基三氮杂环己烷制备RDX[J].火炸药学报,2011,34(1):25-27,3.
