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苯酚分子印迹聚合物的合成、表征及吸附性能研究

黄卫红 陈孝亭 徐婉珍 闫永胜

环境工程学报2011,Vol.5Issue(1):113-116,4.
环境工程学报2011,Vol.5Issue(1):113-116,4.

苯酚分子印迹聚合物的合成、表征及吸附性能研究

Studies on preparation and characteristics of binding and recognition of phenol molecular imprinted polymers

黄卫红 1陈孝亭 1徐婉珍 2闫永胜2

作者信息

  • 1. 江苏大学环境学院,镇江,212013
  • 2. 江苏大学化学化工学院,镇江,212013
  • 折叠

摘要

Abstract

A series of polymers were prepared by bulk polymerization in chloroform. Phenol, 2-vinylpyridine(2-Vpy) and EGDMA (ethylene glycol dimethacrylate) were used as template, functional monomer and cross-linker, respectively. The selectivity and adsorption properties of the plolymers were evaluated by binding experiments. The results indicated that the imprinted factor of the polymer was 3.96, the maximum binding capacity (Qmax) was 120.7 mmol/g and the polymer had the best selectivity and adsorption ability,when chloroform used as the porogenic solvent and the molar ratio of the template to the functional monomer was 1: 2. Polymers were characterized by ultraviolet ( UV ) spectroscopy, Fourier transform infrared spectrometer (FTIR) and scanning electron microscopy(SEM) to study binding and recognition properties.

关键词

分子印迹技术/印迹聚合物/苯酚

Key words

molecular imprinting technology/ molecularly imprinted polymers/ phenol

分类

资源环境

引用本文复制引用

黄卫红,陈孝亭,徐婉珍,闫永胜..苯酚分子印迹聚合物的合成、表征及吸附性能研究[J].环境工程学报,2011,5(1):113-116,4.

基金项目

江苏大学人才基金项目(06JDG030) (06JDG030)

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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