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以碳球为模板合成氧化铈纳米空心球

陈丰 陈志刚 李霞章 陆晓旺 赵晓兵

硅酸盐学报2011,Vol.39Issue(3):397-402,6.
硅酸盐学报2011,Vol.39Issue(3):397-402,6.

以碳球为模板合成氧化铈纳米空心球

Synthesis of CeO2 Hollow Nanosphere Using Carbon Sphere as Template

陈丰 1陈志刚 2李霞章 3陆晓旺 3赵晓兵3

作者信息

  • 1. 江苏大学材料科学与工程学院,江苏,镇江,212013
  • 2. 苏州科技学院化学与生物工程学院,江苏,苏州,215011
  • 3. 江苏工业学院材料科学与工程学院,江苏,常州,213164
  • 折叠

摘要

Abstract

Carbon sphere template with a diameter of about 300 nm was uniformly coated with CeO2 nanoparticles by inorganic precursor self-assembly. The CeO2 hollow nanospheres were obtained after the carbon sphere template was removed through calcination at a suitable temperature. Transmission electron microscope, selected area electron diffraction, field emission scanning electron microscope, X-ray diffraction, X-ray photoelectron spectrum, thermogravimetry and differential thermal analysis were employed to characterize the structure of the CeO2 hollow nanospheres. The results reveal that the face-centered cubic-phase CeO2 hollow nanospheres with a diameter of about 250 nm as well as the thin shell thickness about 20 nm is prepared. It indicates that this material has good decolorizing performance for methylene blue simulative dyeing wastewater. The decolorizmg rate can reach 95% for simulative wastewater after 4 h.

关键词

碳球/氧化铈/模板/自组装/纳米空心球

Key words

carbon sphere/ ceria/ template/ self-assembly/ hollow nanospheres

分类

化学化工

引用本文复制引用

陈丰,陈志刚,李霞章,陆晓旺,赵晓兵..以碳球为模板合成氧化铈纳米空心球[J].硅酸盐学报,2011,39(3):397-402,6.

基金项目

国家自然科学基金(20771047) (20771047)

江苏省自然科学基金(BK2008541)及江苏省工业支撑计划(BE2008033)资助项目. (BK2008541)

硅酸盐学报

OA北大核心CSCDCSTPCD

0454-5648

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