含能材料2011，Vol.19Issue(1)：19-22,4.DOI:10.3969/j.issn.1006-9941.2011.01.005
二茂铁氮杂环衍生物的合成及对高氯酸铵热分解的催化作用
Synthesis of Ferrocenyl Dihydropyrazole Derivatives and their Catalysis on Thermal Decomposition of AP
摘要
Abstract
Three ferrocenyl nitrogenous heterocyclic compounds containing polar functionalities were designed and synthesized,and their structures were characterized by 1 H NMR, IR and MS spectra. The thermal decomposition properties of AP with 5％(weight) of the titled compounds were investigated by differential thermalanalysis (DTA) and thermogravimetry (TG). Results show that the second exothermic peak temperature of AP is reduced by 89.10 ℃ and the temperature difference between the two exothermic peaks can be reduced to 25.82 ℃.关键词
有机化学/二茂铁衍生物/含氮杂环化合物/高氯酸铵/热分解Key words
organic chemistry/ ferrocenyl derivative/ nitrogenous heterocyclic compound/ ammonium perchlorate/ thermal decomposition分类
军事科技引用本文复制引用
高勇,柯成锋,李恒东,谢莉莉,袁耀锋..二茂铁氮杂环衍生物的合成及对高氯酸铵热分解的催化作用[J].含能材料,2011,19(1):19-22,4.基金项目
福建省自然科学基金资助(2009J05023 （）
2009J05028) （）
