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特征化学反应增强的吸附法燃油深度脱硫

王瑞聪 付轶 周理

化工进展2011,Vol.30Issue(2):298-302,5.
化工进展2011,Vol.30Issue(2):298-302,5.

特征化学反应增强的吸附法燃油深度脱硫

Deep desulfurization of transportation fuels enhanced by characteristic reaction occurring in mesoporous adsorbent

王瑞聪 1付轶 2周理2

作者信息

  • 1. 天津大学理学院,天津300072
  • 2. 天津大学化工学院,天津300072
  • 折叠

摘要

Abstract

Commercial gasoline contains several hundreds mg/L sulfur and diesel contains 1000-2000 mg/L sulfur in China, though the fuels have been treated by hydrodesulfurizafion. The high level of sulfur content in fuels makes vehicles emission the major pollution source of urban areas. Considering the sulfur compounds are mainly thiophene and its derivatives after hydrodesulfurizafion, we made a test, in which a characteristic reaction of thiophenic compounds with formaldehyde under catalysis of strong acid occurred in mesoporous adsorbents, and the adsorption of this kind of sulfur compounds was considerably enhanced. Coupled with an oxidation/adsorption treatment, the total sulfur content of commercial fuels dropped to below 15 mg/L.

关键词

深度脱硫/燃油/反应/吸附/缩合/吸附剂

Key words

deep desulfurization/ transportation fuels/ reaction/adsorption/ condensation/ adsorbent

分类

能源科技

引用本文复制引用

王瑞聪,付轶,周理..特征化学反应增强的吸附法燃油深度脱硫[J].化工进展,2011,30(2):298-302,5.

基金项目

国家自然科学基金项目(20776099). (20776099)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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