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复合BaTiO3的Li0.5La0.5TiO3固体电解质的制备和性能

尚随军 邓元 梅骜 林元华 刘丽玉 南策文

电源技术2011,Vol.35Issue(2):176-178,3.
电源技术2011,Vol.35Issue(2):176-178,3.

复合BaTiO3的Li0.5La0.5TiO3固体电解质的制备和性能

Preparation and properties of Lio.5Lao.5TiO3 mixed with BaTiO3

尚随军 1邓元 2梅骜 3林元华 3刘丽玉 2南策文3

作者信息

  • 1. 比克国际(天津)有限公司,天津,300402
  • 2. 北京航空航天大学材料学院,北京,100083
  • 3. 清华大学材料系,北京,100084
  • 折叠

摘要

Abstract

A pure phase of the solid electrolyte Li0.5La0.5TiO3 (LLTO) was prepared by the conventional solid-state reaction method, and those LLTO powders were mixed with BaTiO3 nano particles to prepare the composite. The microstructure morphology and conductivity properties of the composite were investigated by X-ray diffraction,scanning electron microscope and AC impedance method. The grain conductivity of LLTO bulk sample is 1.1 x 10-3S/cm. The perovskite-type solid solution (Li,La,Ba)TiO3 rods can be found in the composite. At the lower dopant concentration (<10%), the grain conductivity of the composite electrolyte is higher than that of the pure LLTO. The grain conductivities of LLTO and LLTO doped with 5 % BaTiO3 at 120 ℃ are 0.84 x 10-2S/cm and 2.39 x 10-2 S/cm respectively.

关键词

钙钛矿/固相法/固体电解质/钛酸镧锂/BaTiO3

Key words

perovskite/ solid-state reaction/ solid-state electrolyte/ lithium lanthanum titanate/ barium titanate

分类

信息技术与安全科学

引用本文复制引用

尚随军,邓元,梅骜,林元华,刘丽玉,南策文..复合BaTiO3的Li0.5La0.5TiO3固体电解质的制备和性能[J].电源技术,2011,35(2):176-178,3.

基金项目

国家自然科学基金项目(50621201) (50621201)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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