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3种配合物的非线性光学性能与分子结构的关系

张鹏飞 石旭刚

激光技术2011,Vol.35Issue(1):79-81,3.
激光技术2011,Vol.35Issue(1):79-81,3.DOI:10.3969/j.issn.1001-3806.2011.01.022

3种配合物的非线性光学性能与分子结构的关系

Relationship between nonlinear optical property and molecular structures of three organometallic complexes

张鹏飞 1石旭刚2

作者信息

  • 1. 浙江工商职业技术学院,工学院,宁波,315012
  • 2. 浙江工业大学,信息学院,杭州,310032
  • 折叠

摘要

Abstract

To explore the influence of molecular structures on the nonlinear optical property, the third-order nonlinear optical property of three organometallic complexes with different central metallic atoms ( Ni, Cu, and Pd) was investigated by means of z-scan technique. After comparing the nonlinear refractive indexes and the excited state absorption cross-sections of the complexes, it was found that the heavy central metallic atom enhanced the third-order optical property obviously, but the resonant absorption did not have much effect on the nonlinear optical property. The experiment results show that all the three complexes have self focusing and reverse saturation absorption characteristics.

关键词

非线性光学/自聚焦/z扫描/金属有机配合物

Key words

nonlinear optics/ self-focusing/ z-scan/ organometallic complexes

分类

数理科学

引用本文复制引用

张鹏飞,石旭刚..3种配合物的非线性光学性能与分子结构的关系[J].激光技术,2011,35(1):79-81,3.

激光技术

OA北大核心CSCDCSTPCD

1001-3806

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