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DOPO衍生物阻燃性能研究

陶志强 丁佳培 宋涛 杨士勇

宇航材料工艺2011,Vol.41Issue(1):89-92,4.
宇航材料工艺2011,Vol.41Issue(1):89-92,4.

DOPO衍生物阻燃性能研究

Research on Flame Retardancy of DOPO Derivative

陶志强 1丁佳培 1宋涛 1杨士勇1

作者信息

  • 1. 中国科学院化学研究所,高技术材料实验室,北京,100190
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摘要

Abstract

Phosphorus-containing organic compounds such as DOPO have several advantages including high flame-retardant efficiency, low production of corrosive and toxic gases in flames etc. In this work, a novel DOPObased siloxanes were evaluated as halogen-free flame retardants for epoxy resins. The cured epoxy resins exhibited better thermal stabilities and greatly improved flame retardant properties due to the presence of phosphorus-containing siloxanes. The cured epoxy resins with phosphorus loading of 2. 0 wt% showed LOI values of 32-33 and achieved UL94 V-O ratings. Silicon and phosphorus demonstrated a synergistic effect in the flame retarding behavior of the resins.

关键词

DOPO/环氧树脂/阻燃/热稳定性

引用本文复制引用

陶志强,丁佳培,宋涛,杨士勇..DOPO衍生物阻燃性能研究[J].宇航材料工艺,2011,41(1):89-92,4.

基金项目

国家自然科学基金(50803069)资助 (50803069)

宇航材料工艺

OA北大核心CSCDCSTPCD

1007-2330

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