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新型纳米结构二氧化锰的制备及其超级电容性能

段立谦 李景印 李玉佩 何前国

河北科技大学学报2011,Vol.32Issue(2):169-172,4.
河北科技大学学报2011,Vol.32Issue(2):169-172,4.

新型纳米结构二氧化锰的制备及其超级电容性能

Preparation and supercapacitive performance of a novel nanostructural MnO2

段立谦 1李景印 1李玉佩 1何前国1

作者信息

  • 1. 河北科技大学理学院,河北石家庄,050018
  • 折叠

摘要

Abstract

Cauliflower MnO2 was prepared by hydrothermal synthesis method by reacting MnSO4 and (NH4)2S2O8 with Fe(NO3)3. The samples were analyzed by X-ray diffraction(XRD) and scanning electron microscopy (SEM). Cyclic voltammetry and galvanostatic charge-discharge were used to characterize the electrochemical performance of the samples. The results show that the prepared samples are α-MnO2. The particles are in a caulillower shape. In an electrolyte of 6 mol/L KOH , electrode based on the MnO2 show perfect supercapacitor characterization in the potential region of 0~0.4 V. At a current density of 100 mA/g , a specific capacitance of 176 F/g is achieved.

关键词

水热法/MnO2/超级电容器/比容量

Key words

hydrothermal synthesis/ MnO2 / supercapacitors/ specific capacitance

分类

化学化工

引用本文复制引用

段立谦,李景印,李玉佩,何前国..新型纳米结构二氧化锰的制备及其超级电容性能[J].河北科技大学学报,2011,32(2):169-172,4.

基金项目

河北科技大学科研基金资助项目(XL200872,XL200908) (XL200872,XL200908)

河北科技大学学报

OACSTPCD

1008-1542

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