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柳杉木材边材木醋液中的成分研究

魏立纲 鲁保旺 马英冲 李中原

林产化学与工业2011,Vol.31Issue(2):12-18,7.
林产化学与工业2011,Vol.31Issue(2):12-18,7.

柳杉木材边材木醋液中的成分研究

Components in Wood-vinegar of Sugi ( Cryptomeria Japonica D. Don) Sapwood

魏立纲 1鲁保旺 2马英冲 1李中原3

作者信息

  • 1. 大连工业大学化工与材料学院,辽宁大连,116034
  • 2. 国立环境研究所循环型社会-废弃物研究中心,筑波305-8506,日本
  • 3. 深圳市计量质量检测研究院,广东深圳,518131
  • 折叠

摘要

Abstract

Thirty-seven components in wood-vinegar obtained from the carbonization of sugi sapwood were determined by capillary gas chromatography(GC).The results showed that main components in sugi wood-vinegar were methanol,ketones, carboxylic cids,furans,phenols and guaiacols.The methods of solvent extraction and silica gel column chromatography were used to further investigate the unknown components in the wood-vinegar.The chiral levoglucosan(LGA,1,6-anhydroβ-D-glucose) as an unknown component was isolated form sugi wood-vinegar, which was not able to be detected by the capillaryGC. 60.5 g LGA can be separated from 150 mL sugi wood-vinegar.The pathway of the formation of major components in sugiwood-vinegar was also analyzed and discussed.

关键词

柳杉树(日本柳杉)边材/木醋液/毛细管气相色谱法/左旋葡聚糖

Key words

(Cryptomeria Japonica D.Don) sapwood/wood-vinegar/capillary gas chromatography/levoglucosan

分类

化学化工

引用本文复制引用

魏立纲,鲁保旺,马英冲,李中原..柳杉木材边材木醋液中的成分研究[J].林产化学与工业,2011,31(2):12-18,7.

基金项目

辽宁省教育厅科学技术项目(20060174) (20060174)

大连市科学计划项目(2008J23JH040) (2008J23JH040)

制浆造纸科学与技术省部共建教育部重点实验室(山东轻工业学院)开放基金资助项目(0810) (山东轻工业学院)

林产化学与工业

OA北大核心CSCDCSTPCD

0253-2417

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