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Fenton试剂强化微电解工艺预处理中纤板热磨废水

张文妍 李凡 孙盼华 张齐生

浙江农林大学学报2011,Vol.28Issue(1):13-17,5.
浙江农林大学学报2011,Vol.28Issue(1):13-17,5.

Fenton试剂强化微电解工艺预处理中纤板热磨废水

Micro-electrolysis treatment for hot, grinding wastewater from MDF production using Fenton's reagent

张文妍 1李凡 1孙盼华 1张齐生1

作者信息

  • 1. 南京林业大学木材工业学院,江苏南京210037
  • 折叠

摘要

Abstract

The hot, grinding wastewater from medium density fiberboard (MDF) production contains high concentrated toxic oranic maters. It is not fit for biochemical treatment even after pretreatment of micro-electrolysis. Fenton's reagent method was employed to improve the former micro-electrolysis treatment by means of jar test. Optimal parameters of the Fenton process were determined as 0.05-0.10 of [Fe2+]/[H2O2] with 1 h reaction time. When Fenton treated effluent was controlled at pH 8.5, the sedimentation process further removed pollutants, and the chemical oxygen demand (COD) concentration of the former micro-electrolysis treatment effluent was reduced from 14 000 mg· L-1 to about 3 500 mg·L-1 . GC-MS analysis indicated that the combined process of micro-electrolysis and Fenton oxidation broke almost all of the monocyclic terpene bonds in the wastewater, oxidizing them to esters, alcohols, and ketones with a lower carbon number. However, for double ring terpense the combined process only broke some of the bonds. These obtained results evidenced the efficiency of the combined process to the hot, grinding wastewater pretreatment and should contribute to further studies of MDF wastewater treatment. [Ch, 5 fig. 1 tab. 13 ref.]

关键词

林业工程/中纤板热磨废水/Fenton试剂/微电解/预处理/气相色谱/质谱联用技术(GC-MS)分析

Key words

forest engineering/ hot, grinding wastewater from medium density fiberboard(MDF) production/Fenton/ micro-electrolysis/ pretreatment/ gas chromatography-mass spectrometry (GC-MS)

分类

农业科技

引用本文复制引用

张文妍,李凡,孙盼华,张齐生..Fenton试剂强化微电解工艺预处理中纤板热磨废水[J].浙江农林大学学报,2011,28(1):13-17,5.

基金项目

江苏省高校科研成果产业化推进工程项目(JH-09-54) (JH-09-54)

浙江农林大学学报

OA北大核心CSCDCSTPCD

2095-0756

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