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一种测定痕量甲醛的催化光度分析方法

郭伟 陈玉婷 孙贤祥 许冬莹

常州大学学报(自然科学版)2011,Vol.23Issue(1):67-70,4.
常州大学学报(自然科学版)2011,Vol.23Issue(1):67-70,4.

一种测定痕量甲醛的催化光度分析方法

Catalytic Sepctrophotometric Method for Determination of Trace Formaldehyde

郭伟 1陈玉婷 1孙贤祥 1许冬莹1

作者信息

  • 1. 常州大学,石油化工学院,江苏,常州,213164
  • 折叠

摘要

Abstract

A simple, catalytic spectrophotometric method for the determination of formaldehyde was proposed, based on the catalytic effect of formaldehyde on oxidation of chlorpromazine hydrochloride-bromate in the presence of phosphoric acid and under optimized experimental conditions. The linear concentration range of formaldehyde determined was 12.0-132.0mg · L-1 and the linear equation about the absorbance difference (△A) versus the concentration (ρ) was ΔA=0. 026 57+0. 002 25ρ (r=0. 993 3). The limit of detection was 0. 19mg · L-1 of formaldehyde. The recoveries and the relative standard deviation (RSD) were 99.4%- 100. 5%, 1.2%- 1.5%, respectively. This method has been successfully used in analysis of the sample solutions containing acetic acid and iodic ion.

关键词

甲醛/催化光度法/盐酸氯丙嗪/溴酸钾/碘离子

Key words

formaldehyde/ kinetic spectrophotometric method/ Chlorpromazine Hydrochloride/ potassium bromate/ iodic ion

分类

化学化工

引用本文复制引用

郭伟,陈玉婷,孙贤祥,许冬莹..一种测定痕量甲醛的催化光度分析方法[J].常州大学学报(自然科学版),2011,23(1):67-70,4.

常州大学学报(自然科学版)

2095-0411

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