石油化工高等学校学报2011，Vol.24Issue(2)：58-61,4.DOI:10.3696/j.issn.1006-396X.2011.02.015
SBA-15在环己烷选择性氧化中的催化研究
Selective Oxidation of Cyclohexane Catalysis in SBA-15
摘要
Abstract
Au/SBA-15, Au-Ni/SBA-15, Au-Co/SBA-15 catalyst were prepared by in situ synthesis and deposition synthesis, and the crystal structure and metal dispersion were characterized by XRD, TEM-EDS and other means.In the condition of absence of any organic solvents or additives, air was used as the oxidant to oxidize cyclohexane selectively, and catalytic properties were evaluated in this reaction.It is found that good synergistic effect exists in the two-metal catalysts for selective oxidation of cyclohexane to cyclohexanone and cyclohexanol, which can greatly increase the catalytic activity.The conversion rate of cyclohexane is 22.1 ％, and the total selectivity of cyclohexanol and cyclohexanone is 95.1 ％, when Au-Co/SBA-15 was used as the catalyst in the condition of 3 MPa, 423 K and 2 hours.关键词
SBA-15/环己烷/表征/协同作用Key words
SBA-15/ Cyclohexane/ Characterization/ Synergistic effect分类
化学化工引用本文复制引用
张晓彤,张翻,高翔,秦玉才,陈雷,宋丽娟..SBA-15在环己烷选择性氧化中的催化研究[J].石油化工高等学校学报,2011,24(2):58-61,4.基金项目
辽宁省教育厅科技项目(2007R29) （2007R29）
国家自然科学基金项目(20976077). （20976077）
