西北师范大学学报（自然科学版）2011，Vol.47Issue(3)：65-69,5.
α-二亚胺Ni(Ⅱ)配合物/二乙基氯化铝催化乙烯聚合的研究
Polymerization of ethylene catalyzed by α-diimine Ni( Ⅱ ) catalyst/diethylaluminium chloride
摘要
Abstract
A new α-diimine compound and its corresponding Ni( Ⅱ )complex, { bis [N, N'-(2, 4-dimethylphenyl) imino] acenaphthene} dibromonickel are successfully synthesized and characterized by 1HNMR, 13CNMR, elemental analysis, FT-IR and XPS. Ethylene polymerization catalyzed by nickel (Ⅱ )complex 2/DEAC system is investigated. The influence of reaction parameter(temperature and Al/Ni mole ratio) on polymerization of ethylene is evaluated. The polymers are characterized by 1HNMR,13CNMR, GPC, TG, DSC. Results show that the catalytic system displays high catalytic efficiency(1.61 × 107 g PE/(mol. Ni. h. MPa), and the polymers are highly branched (119 branches/1000 C).关键词
α-二亚胺镍配合物/后过渡金属催化剂/二乙基氯化铝(DEAC)/乙烯聚合Key words
α-diimine nickel ( Ⅱ ) complex/ late-transition metal catalyst/ diethylaluminium chloride (DEAC) / ethylene polymerization分类
化学化工引用本文复制引用
袁建超,王学虎,刘玉凤,梅铜简..α-二亚胺Ni(Ⅱ)配合物/二乙基氯化铝催化乙烯聚合的研究[J].西北师范大学学报（自然科学版）,2011,47(3):65-69,5.基金项目
国家自然科学基金资助项目(20964003) （20964003）
2010教育部留学回国人员科研启动基金资助项目 （）
2010年人力资源和社会保障部留学人员科技活动项目择优资助项目 （）
