石油化工2011，Vol.40Issue(3)：299-303,5.
节能型天然气转化催化剂的放大研究
Preparation of the Catalyst for Scale-Up Energy-Saving Natural Gas Conversion
摘要
Abstract
A supported energy-saving first stage natural gas conversion catalyst (NLY-1 catalyst) was prepared by a multistep impregnation method and used in the scale-up evaluation apparatus.The effects of the operation conditions on the catalyst performance were studied.The fresh and the used catalysts were characterized by means of TG,XRD and SEM.Under the optimal conditions of reactor inlet 500 -520 ℃ ,reactor outlet 780 -800 ℃ ,pressure 3 MPa,GHSV 3 500 h-1 and mole ratio of water to CH4 2.5 -2.7,NLY-1 catalyst had high stability and the CH4 conversion was in the range of 55％ -61％.The characterization results showed the excellent resistance to carbon-deposition of the catalyst.Compared with the first stage conversion catalyst from Fertilizer Plant of Daqing Petrochemical Company, NLY-1 catalyst shows good prospects.关键词
天然气转化/镍基催化剂/合成气/合成氨Key words
natural gas conversion/ nickel-based catalyst/ syngas/ ammonia synthesis分类
化学化工引用本文复制引用
徐艳,蒋毅,张大伟,肖海成,陈君和,张敏..节能型天然气转化催化剂的放大研究[J].石油化工,2011,40(3):299-303,5.基金项目
中国石油炼油与化工分公司项目(0604A09-01). （0604A09-01）
