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K-Ca-Mg-Cl-H2O体系中硫酸钙结晶介稳区的研究

吴晓琴 孔艳萍

环境工程学报2011,Vol.5Issue(6):1431-1434,4.
环境工程学报2011,Vol.5Issue(6):1431-1434,4.

K-Ca-Mg-Cl-H2O体系中硫酸钙结晶介稳区的研究

Research into crystallization metastable zone property of calcium sulfate in K-Ca-Mg-Cl-H2O system

吴晓琴 1孔艳萍1

作者信息

  • 1. 武汉科技大学化学工程与技术学院,武汉,430081
  • 折叠

摘要

Abstract

The crystallization metastable zone of calcium sulfate in the system of K-Ca-Mg-Cl-H2O was investigated. The supersaturated solution of calcium sulfate was formed by reaction of calcium chloride solution and magnesium sulfate solution with certain concentrations, and the relationship between the supersaturation of calcium sulfate and its crystallization was studied in mixed salt solutions at different salt concentrations and different temperatures by the laser light scattering method. The corresponding solubilities of calcium sulfate were also determined in this system. Accordingly, the width of metastable zone of calcium sulfate crystallization was then determined. Further, the paper investigated the factors influencing the metastable zone, and also the inner connection among calcium sulfate crystallization and its phases with the factors of mixed salt solutions concentration,temperature and the crystallization metastable zone.

关键词

硫酸钙/过饱和度/溶解度/介稳区

Key words

calcium sulfate/ supersaturation/ solubility/ metastable zone

分类

资源环境

引用本文复制引用

吴晓琴,孔艳萍..K-Ca-Mg-Cl-H2O体系中硫酸钙结晶介稳区的研究[J].环境工程学报,2011,5(6):1431-1434,4.

基金项目

国家高技术研究发展计划(863)项目(2006AA06Z385-4) (863)

武汉科技大学杰出青年基金(2008RC06) (2008RC06)

环境工程学报

OA北大核心CSCDCSTPCD

1673-9108

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