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SBA-15的改性及催化文冠果油制备生物柴油

柳杨 衣怀峰 陈宇 吴玉龙 陈曾 杨明德 童军茂

化工进展2011,Vol.30Issue(6):1247-1252,1258,7.
化工进展2011,Vol.30Issue(6):1247-1252,1258,7.

SBA-15的改性及催化文冠果油制备生物柴油

Preparation of bildiesel from sorbifolia oil catalyzed by modified SBA-15

柳杨 1衣怀峰 2陈宇 3吴玉龙 1陈曾 2杨明德 2童军茂1

作者信息

  • 1. 石河子大学食品学院,新疆,石河子,832003
  • 2. 清华大学核能与新能源技术研究院,北京,100084
  • 3. 中国石油新疆油田公司,新疆,克拉玛依,834000
  • 折叠

摘要

Abstract

The supported solid base catalysts KNO3-AlSBA-15 and KNO3-Al-SBA-15, was prepated with mesoporous molecular sieve SBA-15 as carrier, and was loaded with Al and with alkali metal salts KNO3 by direct synthesis and post synthesis respectively. The catalysts were characterized by means of XRD, BET, SEM and CO2-TPD. The result showed that addition of Al had a good protection on the pore structure of catalyst. The alkalinity of catalyst was enhanced significantly after loading KNO3.The transesterification reaction process of sorbifolia oil with the catalyst for biodiesel preparation indicated that KNO3-Al-SBA-15 showed better catalytic activity than traditional catalysts. The biodiesel yield could reach 92%, and this catalyst also showed steady catalytic activity after being reused for many times.

关键词

介孔分子筛/SBA-15/文冠果油/生物柴油/固体碱催化剂

Key words

mesoporous molecular sieve/ SBA-15/ sorbifolia oil/ biodiesel/ solid base catalyst

分类

化学化工

引用本文复制引用

柳杨,衣怀峰,陈宇,吴玉龙,陈曾,杨明德,童军茂..SBA-15的改性及催化文冠果油制备生物柴油[J].化工进展,2011,30(6):1247-1252,1258,7.

基金项目

国家973计划项目(2006CB705809). (2006CB705809)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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