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聚合氯化铝生产废渣的处理与利用

李娜 向浩 鲁义军 陈济美 杜冬云

化工学报2011,Vol.62Issue(5):1441-1447,7.
化工学报2011,Vol.62Issue(5):1441-1447,7.DOI:10.3969/j.issn.0438-1157.2011.05.039

聚合氯化铝生产废渣的处理与利用

Treatment and utilization of waste residue produced from polyaluminium chloride process

李娜 1向浩 1鲁义军 2陈济美 3杜冬云1

作者信息

  • 1. 中南民族大学环境科学与工程研究所,中南民族大学化学与材料科学学院/催化材料科学国家民委-教育部共建重点实验室,湖北武汉430074
  • 2. 东风伟世通(武汉)汽车饰件系统有限公司,湖北武汉430056
  • 3. 湖北省地质实验研究所,湖北武汉430034
  • 折叠

摘要

Abstract

The polyaluminium chloride (PAC) waste residue produced by a company in Hubei province is viscous and colloidal, and of weak acidity and large moisture. If it was piled or landfilled directly,environment would be polluted. The experimental investigation was carried out for treatment and utilization of the waste. Two ways were proposed for modification and utilization of the waste. One is to be used as building materials in stead of part cement to produce fired common brick; the other is to be used as additive of decolorant for refinement of petrochemical. The results show that the acidic mud with pungent swell can be changed to near neutral or neutral, and become odorless, non-toxic and environment-friendly by adding 2% of calcium lime. When the adding amount for modifying waste is within 10%-20%, the fired bricks with it could reach the requirements of the national standard and calcination temperature did reduce about 50-100℃. The modified waste could be used as additive of decolorant. When the ratio of waste/base material was in the range of (1 : 9)-(2: 8), not only the cost of deodorant could be decreased but also the influence on its two main indexes decolorizing ability and surface area was little and its performance could meet the product requirement.

关键词

聚合氯化铝/酸性废渣/普通烧结砖/脱色剂/中和改性/泥浆固化

Key words

PAC/ acidic waste residue/ fired common brick/ decolourant/ neutralization and modification/ mud curing

分类

资源环境

引用本文复制引用

李娜,向浩,鲁义军,陈济美,杜冬云..聚合氯化铝生产废渣的处理与利用[J].化工学报,2011,62(5):1441-1447,7.

基金项目

湖北省自然科学基金重点项目(2009CDA010). (2009CDA010)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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