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多孔C/SiC复合材料的制备及其性能

吉洪亮 张长瑞 周新贵 曹英斌

新型炭材料2011,Vol.26Issue(2):145-150,6.
新型炭材料2011,Vol.26Issue(2):145-150,6.

多孔C/SiC复合材料的制备及其性能

Fabrication and properties of porous C/SiC composites

吉洪亮 1张长瑞 2周新贵 1曹英斌1

作者信息

  • 1. 国防科技大学航天与材料工程学院CFC国防科技重点实验室,湖南长沙410073
  • 2. 中国空气动力研究与发展中心超高速空气动力研究所,四川绵阳622663
  • 折叠

摘要

Abstract

Preforms made of carbon fibers and sacrificial tungsten fibers as a pore forming agent were repeatedly infiltrated with polycarbosilane and pyrolysed for 14 cycles, followed by aqua regia leaching to remove the tungsten fibers to form porous C/SiC composites. The pore structure, mechanical properties and permeability of the porous C/SiC composites to water and kerosene were respectively studied by a scanning electron microscope,a universal materials testing machine and home-made permeation equipment based on a fluid flow model in capillaries. Results showed that the pores of the porous C/SiC composites were mostly straight and that the open porosity can be controlled by the volume fraction of tungsten fibers used. The bend strength , Young's modulus and fracture toughness were 358 MPa, 124 GPa and 16. 7 MPa·m1/2 respectively when the open porosity of the composite was 23. 5% . The fluids permeated through the porous C/SiC composites by linear laminar flow( the osmosis rate value is 1. 02×10-3 mm2 ) . The composites exhibited tough fracture behavior and the presence of pores didn't lead to a significant deterioration of their mechanical properties.

关键词

多孔C/SiC复合材料/孔隙预置技术/开孔率/渗透率

Key words

Porous C/SiC composites/ Prefabricating pore media technology/ Open porosity/ Osmosis rate

分类

通用工业技术

引用本文复制引用

吉洪亮,张长瑞,周新贵,曹英斌..多孔C/SiC复合材料的制备及其性能[J].新型炭材料,2011,26(2):145-150,6.

基金项目

国家863计划(2002AA724064). (2002AA724064)

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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