安徽农业科学2011，Vol.39Issue(11)：6314-6315,6344,3.
苯并香豆素-3-甲酸酯的合成及荧光性研究
Study on Synthesis and Fluorescent Properties of Alkyl Benzocoumarin-3-carboxylates
摘要
Abstract
[ Objective ] The research aimed to study the synthesis and fluorescent properties of alkyl benzocoumarin-3-carboxylates. [ Method ] Alkyl benzocoumarin-3-carboxylates were prepared from 2-hydroxy-1-naphthaldehyde and diethyl malonate by Knoevenagel reaction.The influences of solvents were studied from their UV-visible and fluorescence data.[ Result ] The result showed that alkyl benzocoumarin-3-carboxylates are strong fluorescent compounds and emit bright blue fluorescence.n-Propyl benzocoumarin-3-carboxylate possesses the highest fluorescence quantum yield among these esters.DMSO was used as the fluorescence quenching solvent.As the polarity of the solvent increased,the emission maximum wavelength λem showed little shift.[ Canclusion］The study can lay basis for utilization of alkyl benzocoumarin-3-carboxylates in a large scale.关键词
香豆素/苯并香豆素-3-甲酸酯/合成/荧光Key words
Coumarin/ Alkyl benzocoumarin-3-carboxylates/ Synthesis/ Fluorescence分类
农业科技引用本文复制引用
王忠先,彭明生,宋小平,王飞..苯并香豆素-3-甲酸酯的合成及荧光性研究[J].安徽农业科学,2011,39(11):6314-6315,6344,3.基金项目
海南省自然科学基金项目(808146) （808146）
海南省高等学校科研基金项目(Hj2009-100). （Hj2009-100）
