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碳气凝胶及活化碳气凝胶电极材料制备与性能

袁磊 袁秋月 王朝阳 付志兵 张厚琼 唐永建

强激光与粒子束2011,Vol.23Issue(3):671-674,4.
强激光与粒子束2011,Vol.23Issue(3):671-674,4.DOI:10.3788/HPLPB20112303.0671

碳气凝胶及活化碳气凝胶电极材料制备与性能

Preparation and performance of carbon aerogel and activated carbon aerogel as electrode materials

袁磊 1袁秋月 2王朝阳 1付志兵 1张厚琼 1唐永建1

作者信息

  • 1. 中国工程物理研究院,激光聚变研究中心,四川,绵阳,621900
  • 2. 西南科技大学,材料科学与工程学院,四川,绵阳,621002
  • 折叠

摘要

Abstract

Carbon aerogel(CA) was prepared by the polycondensation of resorcinol(R) and formaldehyde(F) and then activated by CO2 flow.XRD analysis indicates that in the process of activation, CO2 infiltrates into the network of CA and weakens the (002) and (100) peaks.SEM analysis shows that the CO2 activation does not destroy the framework of CA but adds a great number of nano miropores, and accordingly the specific surface area and micropore proportion of CA are greatly improved.Electrochemical characterization was performed using cyclic voltammetry and chronopotentiometry in 1 mol/L KOH aqueous solution electrolyte.The CA electrode with and without activation has a stable electrochemistry performance and preferable reversibility.The specific capacitance of CA is 103 F/g before activation, and reaches 371 F/g after activation due to the increase in specific area.

关键词

超级电容器/碳气凝胶/比电容/循环伏安

Key words

supercapaeitor/ carbon aerogels/ specific capacitance/ cyclic voltammograms

分类

化学化工

引用本文复制引用

袁磊,袁秋月,王朝阳,付志兵,张厚琼,唐永建..碳气凝胶及活化碳气凝胶电极材料制备与性能[J].强激光与粒子束,2011,23(3):671-674,4.

基金项目

中国工程物理研究院科学技术发展基金项目(2009A0302020) (2009A0302020)

强激光与粒子束

OA北大核心CSCDCSTPCD

1001-4322

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