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LiFePO4/CNT复合材料的制备及电化学性能

张勇 杜培培 王力臻 张爱勤 宋延华 李晓峰

北京科技大学学报2011,Vol.33Issue(2):205-209,5.
北京科技大学学报2011,Vol.33Issue(2):205-209,5.

LiFePO4/CNT复合材料的制备及电化学性能

Synthesis and electrochemical performances of LiFePO4/CNT composite materials

张勇 1杜培培 1王力臻 1张爱勤 1宋延华 1李晓峰1

作者信息

  • 1. 郑州轻工业学院河南省表界面科学重点实验室,郑州450002
  • 折叠

摘要

Abstract

LiFePO4/carbon nanotube (CNT) composite cathode materials were synthesized by a sol-gel-microwave method. The effects of microwave time and CNT content on the electrochemical properties of LiFePO4/CNT were studied and the crystal structure and surface morphology were characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that the samples with better electrochemical performance are obtained when the CNT content in LiFePO4/CNT is 2% and the microwave time is 18 min. When charge-discharge cycling at 0.1 C, the initial specific discharge capacity is 142 mAh·g-1 and the specific capacity at the l0th cycle is 136mAh·g-1.

关键词

锂电池/正极材料/碳纳米管/溶胶凝胶法/微波加热

Key words

lithium batteries/ cathode materials/ carbon nanotubes/ sol-gel process/ microwave heating

分类

信息技术与安全科学

引用本文复制引用

张勇,杜培培,王力臻,张爱勤,宋延华,李晓峰..LiFePO4/CNT复合材料的制备及电化学性能[J].北京科技大学学报,2011,33(2):205-209,5.

基金项目

国家自然科学基金资助项目(No.21001097) (No.21001097)

河南省科技厅基础与前沿技术研究项目(No.102300410107) (No.102300410107)

河南省高等学校青年骨干教师资助计划项目(豫教高[2009]844号) (豫教高[2009]844号)

郑州市科技攻关项目(No.0910SGYG23259) (No.0910SGYG23259)

郑州市金水区科技攻关项目(金科字[2009]35号(35)) (金科字[2009]35号(35)

北京科技大学学报

OA北大核心CSCDCSTPCD

2095-9389

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