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激发剂对天然硬石膏水化作用的影响

翟红侠 陈凤琴 张新会

岩石矿物学杂志2011,Vol.30Issue(2):301-306,6.
岩石矿物学杂志2011,Vol.30Issue(2):301-306,6.

激发剂对天然硬石膏水化作用的影响

The influence of the activator on the hydration property of natural anhydrite

翟红侠 1陈凤琴 2张新会1

作者信息

  • 1. 安徽建筑工业学院材料与化学工程学院,安徽,合肥,230601
  • 2. 武汉理工大学材料科学与工程学院,湖北,武汉,430070
  • 折叠

摘要

Abstract

China has very rich resources of anhydrite, and anhydrite resources only in Hanshan of Anhui Province has reached 60 million tons.The development of natural anhydrite as a binding material has important research value in developing low carbon economy and energy conservation.The composition, structure and hydration hardening performance of natural anhydrite were analyzed in this paper.The activity and improvement of the activity of natural anhydrite by adding different activators were studied.Hydrous mechanisms of natural anhydrite were also analyzed.Taking natural anhydrite ( Ⅱ type anhydrous gypsum) produced by Hanshan County of Anhui Province as the major raw material, the influences of five kinds of chemical activators(K2SO4, FeSO4· 7H2O, CaO, Na2C2O4 and calcined alum) on the hydration property of natural anhydrite were investigated.The hydration rates of anhydrite with different contents were detected using the gravimetric method.The composition and microstructure of hydrated products of natural anhydrite were characterized by XRD and SEM.The activated mechanism of hydration activity of natural anhydrite was further discussed.The experimental results indicate that the chemical activator the authors used could obviously promote the hydration rate of natural anhydrite, and the crystal microstructure of the hydration and hardened body was also notably improved after doping activator.The natural anhydrate mixed with 5.0% calcined alum had very good activating action on hydraion.28 days later, the hydration rate reached 74.32 %.

关键词

天然硬石膏/活性/激发剂/水化率/晶体形貌

分类

化学化工

引用本文复制引用

翟红侠,陈凤琴,张新会..激发剂对天然硬石膏水化作用的影响[J].岩石矿物学杂志,2011,30(2):301-306,6.

基金项目

安徽省教育厅自然科学研究重点项目(KJ2010A059). (KJ2010A059)

岩石矿物学杂志

OA北大核心CSCDCSTPCD

1000-6524

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