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白光LED用高亮度橙色高温相Ca3SiO4Cl2:Eu2+荧光粉

丁唯嘉 林委青 张梅 王静 苏锵

中山大学学报(自然科学版)2011,Vol.50Issue(2):62-65,69,5.
中山大学学报(自然科学版)2011,Vol.50Issue(2):62-65,69,5.

白光LED用高亮度橙色高温相Ca3SiO4Cl2:Eu2+荧光粉

An Intense Orange High-temperature Phase Ca3SiO4Cl2: Eu2+ Phosphor for White LEDs

丁唯嘉 1林委青 2张梅 1王静 3苏锵2

作者信息

  • 1. 华南农业大学理学院生物材料研究所,广东广州,510642
  • 2. 中山大学化学与化学工程学院,广东广州,510275
  • 3. 五邑大学功能材料研究所,广东江门,529020
  • 折叠

摘要

Abstract

An intense orange high-temperature phase Ca3SiO4Cl2: Eu2+ phosphor was synthesized by high-temperature solid-state reactions and investigated by photoluminescence excitation, emission spectroscopies and lifetime. The excitation and emission spectra showed that the phosphor could be efficiently excited by the incident light of 300 ~ 450 nm, well matched with the emission band of 395 nm-emitting InGaN chip, and emitted an intense orange light. The fluorescence lifetimes values of Eu2 + ion were determined to be 1.53 μs and 7.29 μs, respectively. By combining the phosphor with a 395 nm-emitting InGaN chip, an intense orange LED was fabricated. Under 20 mA forward-bias current, its CIE chromaticity coordinates were (0.533, 0.446). The result showed that high-temperature phase Ca3SiO4Cl2:Eu2+ was a promising orange phosphor for n-UV InGaN-based white LED.

关键词

白光LED/碱土卤硅酸盐/稀土

分类

数理科学

引用本文复制引用

丁唯嘉,林委青,张梅,王静,苏锵..白光LED用高亮度橙色高温相Ca3SiO4Cl2:Eu2+荧光粉[J].中山大学学报(自然科学版),2011,50(2):62-65,69,5.

基金项目

国家自然科学基金面上资助项目(20501023) (20501023)

广东高校优秀青年创新人才培养计划(育苗工程)资助项目(LYM09031) (育苗工程)

华南农业大学211工程重点学科建设资助项目(2009B010100001) (2009B010100001)

华南农业大学校长科学基金资助项目(2007K031) (2007K031)

中山大学学报(自然科学版)

OA北大核心CSCDCSTPCD

0529-6579

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