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介孔分子筛载体在油品深度加氢脱硫中的应用研究进展

任艳群 王冲 莫家乐 谭艳芝 奚红霞

化工进展2011,Vol.30Issue(4):743-752,10.
化工进展2011,Vol.30Issue(4):743-752,10.

介孔分子筛载体在油品深度加氢脱硫中的应用研究进展

Review of application of mesoporous molecular sieves in deep hydrodesulfurization of oil products

任艳群 1王冲 2莫家乐 1谭艳芝 1奚红霞1

作者信息

  • 1. 华南理工大学化学与化工学院,广东,广州,510640
  • 2. 湖南大学化学化工学院,湖南,长沙,410082
  • 折叠

摘要

Abstract

In recent years mesoporous molecular sieves have been widely used as catalyst supports for deep hydrodesulfurization ( HDS ) of oil products because of their ordered pore structure, narrow pore size distribution, large surface area, high thermal and hydrothermal stability. In this paper, the advance in application of mesoporous molecular sieves MCM, SBA, HMS, KIT, etc., in deep hydrodesulfurization of oil products is reviewed. The effects of the different modified methods of mesoporous molecular sieves, including incorporation of metals and oxides, modification of acid,addition of phosphorus, and recombination of other supports, on the structure, morphology and dispersion of the catalyst and active phase, acidity of the catalyst, interaction of active phase with support, and the HDS catalytic activity are investigated. Furthermore, the advantages and existing problems of mesoporous molecular sieves as HDS catalyst supports are discussed, and future applied prospects are forecasted.

关键词

介孔分子筛/加氢脱硫/催化剂/载体/油品

Key words

mesoporous molecular sieves/ hydrodesulfurization (HDS)/ catalysts/ support/ oil products

分类

化学化工

引用本文复制引用

任艳群,王冲,莫家乐,谭艳芝,奚红霞..介孔分子筛载体在油品深度加氢脱硫中的应用研究进展[J].化工进展,2011,30(4):743-752,10.

基金项目

国家自然科学基金(20876061)及中央高校基本科研业务费专项资金项目. (20876061)

化工进展

OA北大核心CSCDCSTPCD

1000-6613

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