化工进展2011，Vol.30Issue(4)：701-708,8.
水合物法分离二氧化碳的研究现状
Research on hydrate-based carbon dioxide separation
摘要
Abstract
The present situation and research on hydrate-based carbon dioxide separation from the flue gases emitted from fossil fuel power plants or from the IGCC syngas are introduced in this paper,including selection of the promoter or the additive, CO2 separation and capture process, and cost accounting. TBAB and THF are found to be the effective promoter and additive to improve rate of hydrate formation, to reduce the operating pressure, and to enhance CO2 recovery. Based on the research of TBAB and THF, hydrate separation and capture processes combined with chemical absorption or membrane separation are proposed. The cost of capturing 1 ton CO2 of the proposed process is about USD 26, which is lower than simply chemical absorption by about 31％. With further research, the cost can be reduced and the hydrate based CO2 separation and capture process could be promising in future.关键词
水合物/CO2分离与捕集/促进剂/分离效率/烟气/IGCC合成气Key words
hydrate/ CO2 separation and capture/ promoter/ recovery/ flue gas/ IGCC syngas分类
化学化工引用本文复制引用
徐纯刚,李小森,陈朝阳..水合物法分离二氧化碳的研究现状[J].化工进展,2011,30(4):701-708,8.基金项目
国家自然科学基金(20773133,51076155)、广东省科技计划(2009B050600006)及中科院知识创新工程重要方向项目(KGCX2-YW-3X6). （20773133,51076155）
