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CO《,2》在碳酸二甲酯混合溶剂中的溶解度

李铁枝 胡晖 汤志刚

化学工程2011,Vol.39Issue(3):54-58,5.
化学工程2011,Vol.39Issue(3):54-58,5.

CO《,2》在碳酸二甲酯混合溶剂中的溶解度

Solubility of C02 in dimethyl carbonate mixed solvents

李铁枝 1胡晖 1汤志刚2

作者信息

  • 1. 福州大学,化学化工学院,福建,福州,350002
  • 2. 清华大学,化学工程系,化学工程联合国家重点实验室,北京,100084
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摘要

Abstract

To enhance CO2 solubility in solvent and reduce the costs of solvent, a certain amount of aqueous ammonia and cosolvent were added into dimethyl carbonate (DMC) to form quasi-homogeneous mixed C02absorbent.The pedormance of mixed solvents ( DMC + mass fraction 10% aqueous ammonia + diethylene glycol monoethyl ether) was tested by the constant volume method under the different conditions, such as kinds of cosolvent, ratio of diethylene glycol ether, mass fraction of aqueous ammonia, aqueous ammonia ratio and temperature.The results show that the solubility of CO2 in DMC mixed with the other solvent increases with rise of ammonia mass fraction.Under normal pressure, the solubility of CO2 in the mixed solvents of V(DMC) : V ( 10%aqueous anunonia) : V (diethylene glycol monoethyl ether) =70: 15: 15 is 3 times higher than that in DMC.

关键词

CO2/DMC/氨水/二乙二醇乙醚/溶解度

Key words

CO2/ DMC/ aqueous ammonia/ diethylene glycol monoethyl ether/ solubility

分类

化学化工

引用本文复制引用

李铁枝,胡晖,汤志刚..CO《,2》在碳酸二甲酯混合溶剂中的溶解度[J].化学工程,2011,39(3):54-58,5.

化学工程

OA北大核心CSCDCSTPCD

1005-9954

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