燃料化学学报2011，Vol.39Issue(3)：219-223,5.
Ni-Fe/γ-Al2O3双金属催化剂的制备及其CO甲烷化性能研究
Preparation of bimetallic Ni-Fe/γ-Al2O3 catalyst and its activity for CO methanation
摘要
Abstract
Bimetallic Ni-Fe/γ-Al2O3 catalyst and monometallic Ni/γ-Al2O3, Fe/γ-Al2O3 catalysts were prepared by wet impregnation method; they were characterized by XRD, N2 physisorption, H2-TPR, H2-TPD and TPSR. The activity of these catalysts in CO methanation was investigated in a fixed-bed continuous flow reactor. A significant Ni-Fe interaction is observed in the bimetallic Ni-Fe/γ-Al2O3 catalyst; Ni-Fe alloy is formed during reduction, which can promote the adsorption of hydrogen. Under the reaction conditions of 0.5 ％ CO, GHSV of 5 000 h-1 and atmosphere pressure, the bimetallic Ni-Fe/γ-Al2O3 catalyst exhibits high catalytic activity; CO can be completely converted into methane at 220 ℃.关键词
双金属催化剂/Ni-Fe/γ-Al2O3/CO甲烷化Key words
bimetallic catalyst/ Ni-Fe/γ-Al2O3/ CO methanation分类
化学引用本文复制引用
王宁,孙自瑾,王永钊,高晓庆,赵永祥..Ni-Fe/γ-Al2O3双金属催化剂的制备及其CO甲烷化性能研究[J].燃料化学学报,2011,39(3):219-223,5.基金项目
山西省科技创新计划项目(2007101008). （2007101008）
