物理化学学报2011，Vol.27Issue(5)：1195-1200,6.
新型可溶性酞菁的合成和光致发光及电致发光性质
Photoluminescence and Electroluminescence of the Novel Soluble Zinc Phthalocyanine
摘要
Abstract
α(β)-tetra-(methoxy-phenoxy)-zinc phthalocyanine are synthesized by employing 3(4)-nitrobenzene-1,2-dicarbonitrile as precursors.They are characterized by spectrum methods and elemental analysis.The UV-Vis spectrum, photoluminescence spectra of spin-coated film and solid pellet are compared.The electroluminescent devices are fabricated by using spin coating.The results indicate that the fluorescence of solid phthalocyanine has a red-shift of more than 145 nm compared to that in solution.The fluorescences are broader in solid state than that in solution.The fluorescence of β-substituted phthalcyanines has a more red-shift than α-substituted phthalcyanines.The electroluminescent spectra around 856 and 862 nm are consisted with the photoluminescence spectra of spin-coated film.The shorter inter-molecule space leads to the large red-shift of the fluorescence.关键词
可溶性酞菁/合成/光致发光/电致发光/红移Key words
Soluble phthalocyanine/ Synthesis/ Photoluminescence/ Electroluminescence/ Red-shift分类
化学化工引用本文复制引用
白青龙,张春花,程传辉,李万程,申人升,杜国同..新型可溶性酞菁的合成和光致发光及电致发光性质[J].物理化学学报,2011,27(5):1195-1200,6.基金项目
国家自然科学基金(60807009),中央高校基本科研业务费专项资金和高等学校博士学科点专项科研基金(200801411038)资助项目 （60807009）
