河南理工大学学报（自然科学版）2011，Vol.30Issue(1)：100-103,4.
一种锂锌硼磷酸盐的晶体结构
Crystal structure of a lithium zinc borophosphate
摘要
Abstract
A borophosphate compound Li[ ZnBP2O8( H2O)2 ] · H2O, was prepared by hydrothermal synthesis. X - ray single crystal diffraction analysis shows that the crystal structure of Li[ ZnBP2O8 ( H2O)2 ] ·H2O is hexagonal, space group is P6,22 with Z = 6. Mr = 1956. 72, a = 0. 944 67 ( 8) nm, c = 1. 563 97 ( 13)nm , V = 1. 208 70( 18) nm3 , Dc = 2. 688 g/cm3 , F( 000) = 966, R = 0. 033 2 , Wr = 0. 073 0, and 768 reflections is observed within I＞ 2σ(I) . The crystal structure of the compound contains infinite one - dimensional borophosphate ribbons 1∞ [ BP2O8 ] 3- , which is built by BO4 and PO4 tetrahedra arranged around 65 screw axes.关键词
硼磷酸盐/单晶/结构/水热合成Key words
borophosphate/ single crystal/ structure/ hydrothermal synthesis分类
化学化工引用本文复制引用
张爱芸,张丽娜,郑娟..一种锂锌硼磷酸盐的晶体结构[J].河南理工大学学报（自然科学版）,2011,30(1):100-103,4.基金项目
河南省高校骨干教师项目(2008649082) （2008649082）
