物理学报2011，Vol.60Issue(3)：201-206,6.
哒嗪分子表面增强拉曼效应下键极化率的研究:吸附构型与增强机理
Surface enhanced Raman scattering of pyridazine molecule:absorption configuration and enhancement mechanism via bond polarizabilities
摘要
Abstract
The temporal molecular bond polarizabilities of pyridazine molecule absorbed on Ag electrode were explored from its surface enhanced Raman intensities, showing that the two nitrogen atoms are the absorption sites and the enhancement is dominated by the charge transfer mechanism.The behaviors of the charges on the skeletal bonds were demonstrated under various applied voltages, which shows the conjugation effect.This algorithm is universal for the surface systems as long as their Raman spectra are available.关键词
哒嗪/拉曼峰强/时间分辨键极化率/弛豫特征时间Key words
pyridazine/ Raman intensity/ temporal bond polarizability/ relaxation of bond polarizability引用本文复制引用
房超,吴国祯..哒嗪分子表面增强拉曼效应下键极化率的研究:吸附构型与增强机理[J].物理学报,2011,60(3):201-206,6.基金项目
教育部重点实验室基金(批准号:306020),高等学校博士学科点专项科研基金(批准号:20060003050),国家自然科学基金(批准号:20773073)资助的课题. （批准号:306020）
