固体火箭技术2011，Vol.34Issue(2)：207-210,4.
AP/二茂铁衍生物混合体系的热感度研究
Study on thermal sensitivity of AP and ferrocene derivative mixtures
王宁 1赵孝彬 1罗岚 1李彦荣 1段卫毅1
作者信息
- 1. 航天工业固体推进剂安全技术研究中心,襄阳,441003
- 折叠
摘要
Abstract
Thermal sensitivity of AP and ferrocene derivative (EMT) mixtures was studied by partial thermal sensitivity and DSC-TG coupling. The results indicate that reducing AP particle size or increasing the content of EMT can shorten the gap between high-temperature thermal decomposition peak of AP and low-temperature thermal decomposition peak of AP, enhance the low-temperature thermad decomposition amount of AP,and increase partial thermal sensitivity about mixtures of AP and EMT. In the presence of AP, side-chain of EMT is easily ruptured. Residual main skeleton, ferrocene or ferrocene ion, is the real catalyst to thermal decomposition of AP. Furthermore, EMT inhabits proton transfer process of AP, but it is a strong catalysis of EMT to decomposition of HCIO4, one of initial decomposition product of AP.关键词
高氯酸铵/二茂铁衍生物/局部热感度/热分解Key words
AP/ ferrOcene derivative/ partial thermal sensitivity/ thermal decomposition分类
航空航天引用本文复制引用
王宁,赵孝彬,罗岚,李彦荣,段卫毅..AP/二茂铁衍生物混合体系的热感度研究[J].固体火箭技术,2011,34(2):207-210,4.
