固体火箭技术2011，Vol.34Issue(2)：214-219,6.
纳米NiO/MgO的制备及其对AP热分解催化性能影响
Preparation of nanometer NiO/MgO and its catalytic performance for thermal decomposition of ammonium perchlorate
摘要
Abstract
The nanometer NiO/MgO composite particles were prepared via impregnation method. The phase and morphology of NiO/MgO composites were characterized by X-ray diffraction, transmission electron microscopy and energy dispersive X-Ray spectroscopy. The catalysis of nanometer particles ( NiO, MgO), NiO + MgO mixture particles and NiO/MgO composite particles the thermal decomposition of ammonium perchlorate (AP) was investigated by DSC. The Results show that NiO particles are highly dispersed on the MgO support. Catalytic performance of the obtained nanometer NiO/MgO composite particles is superior to that of corresponding single ingredient and NiO + MgO mixture particles. Nanometer NiO/MgO can make the high-temperature decomposition peak value of AP decrease by 92.2 ℃ and the temperature difference value between the low and high temperature decomposition peak reduce up to 10. 6 ℃, which indicates good catalytic performance. The supporting effect of the nanometer MgO can effectively prevent the aggregation of NiO particles and increase the active sites.关键词
纳米NiO/MgO复合粒子/高氯酸铵/热分解/催化Key words
nanometer NiO/MgO/ammonium perchlorate/thermal decomposition/catalysis分类
航空航天引用本文复制引用
谈玲华,李勤华,杭祖圣,潘仁明,姜炜,李凤生..纳米NiO/MgO的制备及其对AP热分解催化性能影响[J].固体火箭技术,2011,34(2):214-219,6.基金项目
国家自然科学基金资助项目(50972060) （50972060）
江苏省2009年度普通高校研究生科研创新计划资助项目(CX09B_095Z) （CX09B_095Z）
南京理工大学自主科研专项计划资助项目(2010ZYTS015). （2010ZYTS015）
