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首页|期刊导航|应用化学|碳酸钙粒子增韧高密度聚乙烯的脆韧转变——Wu氏增韧理论聚合物共混物脆韧转变判据的适用条件

碳酸钙粒子增韧高密度聚乙烯的脆韧转变——Wu氏增韧理论聚合物共混物脆韧转变判据的适用条件

胡跃鑫 冯玉林 姜伟

应用化学2011,Vol.28Issue(5):500-503,4.
应用化学2011,Vol.28Issue(5):500-503,4.DOI:10.3724/SP.J.1095.2011.00521

碳酸钙粒子增韧高密度聚乙烯的脆韧转变——Wu氏增韧理论聚合物共混物脆韧转变判据的适用条件

High-density Polyethylene Toughened with Calcium Carbonate Particles——Applicability of Wu'Criterion for Brittle-Ductile Transition of Polymer Blends

胡跃鑫 1冯玉林 2姜伟1

作者信息

  • 1. 中国科学院长春应用化学研究所,高分子物理与化学国家重点实验室,长春,130022
  • 2. 中国科学院研究生院,北京
  • 折叠

摘要

Abstract

High density polyethylene was toughened by calcium carbonate ( CaCO3) with different particle sizes. The relationship between critical interparticle distance (IDc) and CaCO3 content and particle size was studied at different temperatures. The purpose is to clarify that temperature is one of the important parameters for applicability of Wu's criterion. The results indicate that the IDc is almost independent of CaCO3 content and particle size at 17 ℃, that is, the criterion is applicable to this case. With an increase in the temperature, the results clearly show that IDc depends on the CaCO3 particle size at higher temperatures, that is, the criterion is inapplicable at higher temperatures.

关键词

聚合物增韧/粒子间距/脆韧转变

Key words

toughening polymer,interparticle distance,brittle-ductile transition

分类

化学化工

引用本文复制引用

胡跃鑫,冯玉林,姜伟..碳酸钙粒子增韧高密度聚乙烯的脆韧转变——Wu氏增韧理论聚合物共混物脆韧转变判据的适用条件[J].应用化学,2011,28(5):500-503,4.

基金项目

吉林省科技发展计划项目(20080506) (20080506)

应用化学

OA北大核心CSCDCSTPCD

1000-0518

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