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还原氧化石墨烯修饰Bi2WO6提高其在可见光下的光催化性能

应红 王志永 郭政铎 施祖进 杨上峰

物理化学学报2011,Vol.27Issue(6):1482-1486,5.
物理化学学报2011,Vol.27Issue(6):1482-1486,5.

还原氧化石墨烯修饰Bi2WO6提高其在可见光下的光催化性能

Reduced Graphene Oxide-Modified Bi2WO6 as an Improved Photocatalyst under Visible Light

应红 1王志永 2郭政铎 2施祖进 2杨上峰2

作者信息

  • 1. 中国科学技术大学材料科学与工程系,合肥微尺度物质科学国家实验室,中国科学院能量转换材料重点实验室,合肥230026
  • 2. 北京大学化学与分子工程学院,稀土材料化学与应用国家重点实验室,北京分子科学国家实验室,北京100871
  • 折叠

摘要

Abstract

A new and improved photocatalyst, reduced graphene oxide (RGO)-modified Bi2WO6 (Bi2WO6-RGO), was synthesized by a two-step hydrothermal process. The effect of RGO content on photoactivity was investigated and the optimum mass ratio of RGO to Bi2WO6 was determined to be 1 %. Based on scanning electron microscopic study, RGO does not change the structure and morphology of the Bi2WO6 photocatalyst. Therefore, the improvement in the photoactivity of the Bi2WO6-RGO composite is undoubtedly ascribed to RGO. The presence of graphene can facilitate the dissociation of photogenerated excitons, which leads to more O·-2 to degrade dye pollutants like rhodamine-B (RhB). Moreover, the efficient adsorption of RhB molecules on graphene is another reason for the improved photoactivity.

关键词

Bi2WO6/石墨烯/水热法/光催化剂/有机染料污染物

Key words

Bi2WO6/Graphene/Hydrothermal process/Photocatalyst/Dye pollutant

分类

化学化工

引用本文复制引用

应红,王志永,郭政铎,施祖进,杨上峰..还原氧化石墨烯修饰Bi2WO6提高其在可见光下的光催化性能[J].物理化学学报,2011,27(6):1482-1486,5.

基金项目

国家自然科学基金(20771010,20801052),国家重点基础研究发展规划项目(973)(2011CB932601)国家高技术研究发展计划项目(863)(2007AA03Z311)和中国科学院百人计划(A1010)资助The project was supported by the National Natural Science Foundation of China (20771010,20801052),National Key Basic Research Program of China (973) (2011CB932601),National High Technology Research and Development Program of China (863) (2007AA03Z311),and "100 Talents Program of Chinese Academy of Sciences" (A 1010). (20771010,20801052)

物理化学学报

OA北大核心CSCDCSTPCDSCI

1000-6818

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