高校化学工程学报2011，Vol.25Issue(3)：390-394,5.
间苯二甲腈在四种溶剂中溶解度的测定及关联
Measurement and Correlation of the Solubility of Isophthalonitrile in Four Solvents
李玉刚 1孔令启 1马磊 1张道斌 1周波2
作者信息
- 1. 青岛科技大学,计算机与化工研究所,山东青岛266042
- 2. 青岛银科恒远化工过程信息技术有限公司,山东青岛266042
- 折叠
摘要
Abstract
The solubility data of isophthalonitrile (IPN) in methanol, toluene, dimethylbenzene and aniline at 293.15～381.15 K were determined by equilibrium method. The experimental data were correlated with λ-h equation, Apelblat equation and Yaws equation, respectively. According to the experimental data, the solubilities of IPN in above mentioned 4 solvent systems increase with increasing temperature, and they are of great difference in different solvents. Comparing 24 data of IPN solubility in above 4 solvent systems, the average absolute deviations between the experimental values of IPN solubility and those calculated by above three equations are 5.92％, 3.90％ and 3.86％, respectively. The results show that all the λ-h equation, Apelblat equation and Yaws equation could well correlate the solubility data of IPN in those 4 mentioned solvents.关键词
间苯二甲腈/固液平衡/溶解度/溶解度模型Key words
isophthalonitrile (IPN)/ solid-liquid equilibrium/ solubility/ solubility model分类
化学化工引用本文复制引用
李玉刚,孔令启,马磊,张道斌,周波..间苯二甲腈在四种溶剂中溶解度的测定及关联[J].高校化学工程学报,2011,25(3):390-394,5.
