高校化学工程学报2011，Vol.25Issue(3)：501-506,6.
聚离子液体/PVDF共混离子传导膜的制备与性能研究
Ion Conductive Membrane with Interpenetration Network (IPN) Prepared by PVDF/Poly(Ionic Liquid)s Blend
摘要
Abstract
Ionic liquids (ILs) are organic salts with low melting point (＜ 100℃), low flammability, negligible vapor pressure, high ionic conductivity and wide electrochemical window. Polymeric ionic liquids (PILs) are a class of ionic liquids that contain polymerizable groups such as double bonds. In this article, ion conductive membrane with interpenetration network (IPN) was prepared by using the polyvinylidene fluoride(PVDF) and PILs. The conductivity of the prepared membrane depends on the adding amount of ionic liquid, and also depends on the type of added ionic liquid. In addition, the adding amount of ionic liquids has a significant effect on the tensile strength of the prepared membrane. As the mass ratio of PILs to PVDF is 0.6, the membrane conductivity reaches 3.0× 10-3 S·cm-1, the tensile strength 17.38 N·mm-2.关键词
聚离子液体/聚偏氟乙烯/离子传导膜/面电阻/拉伸强度Key words
polymeric ionic liquids/ PVDF/ ion conductive membrane/ area resistance/ tensile strength分类
通用工业技术引用本文复制引用
青格乐图,刘平,范永生,徐冬清,王保国..聚离子液体/PVDF共混离子传导膜的制备与性能研究[J].高校化学工程学报,2011,25(3):501-506,6.基金项目
国家自然科学基金(20876086,20176112) （20876086,20176112）
国家"863"课题(2007AA05Z245):国家重点基础研究发展计划(973计划)项目(2010CB227202). （2007AA05Z245）
