电化学2011，Vol.17Issue(2)：227-230,4.
茴香醛的直接电氧化合成研究
Study on the Direct Electro-Oxidation of Anisaldehyde
摘要
Abstract
The direct electro-oxidation of anisole on Pt electrode was investigated by cyclic voltammery and constant potential electrolysis. The influences of scan rate, substrate concentration, supporting electrolyte and solvent were studied. The products of constant potential electrolysis were charactered by GC-MS. The results show that the electro-oxidation process of anisole was irreversible. In this research the sulfuric acid was the best supporting electrolytes and acetone was the best solvent. The process was controlled by diffusion. The main products were anisaldehyde,and the selectivity was up to 66.5％ when using acetone as a solvent.关键词
茴香醚/电氧化/茴香醛Key words
anisole/ electro-oxidation/ anisaldehyde分类
化学化工引用本文复制引用
吴玲玲,朱英红,李姗姗,曾红燕,马淳安..茴香醛的直接电氧化合成研究[J].电化学,2011,17(2):227-230,4.基金项目
浙江省重点科技创新团队(2009R50002)项目资助 （2009R50002）
