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甲烷水合物再汽化分解动力学模型建立

庞维新 孙福街 李清平 陈光进

化工学报2011,Vol.62Issue(7):1906-1914,9.
化工学报2011,Vol.62Issue(7):1906-1914,9.DOI:10.3969/j.issn.0438-1157.2011.07.018

甲烷水合物再汽化分解动力学模型建立

Kinetic model investigation of regasification of methane hydrate

庞维新 1孙福街 2李清平 1陈光进1

作者信息

  • 1. 中海油研究总院,北京,100027
  • 2. 中国石油大学(北京)重质油国家重点实验室,北京,102249
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摘要

Abstract

Hydrate regasification experimental study were performed for gas storage as hydrate, and the effect of temperature, dissociation pressure and hydrate quantity on hydrate dissociation rate were studied. The results indicated that hydrate dissociation rate decreased because of a buffering effect when the hydrate quantity was large in the reactor, but dissociation rate could increase by lowering dissociation pressure, and hydrate dissociation rate was controlled by the driving force of dissociation, which depended on heat transfer rate and dissociation pressure. According to the mechanism analysis of hydrate regasification, a model of regasification of methane hydrate was proposed based on heat transfer and equation of hydrate dissociation rate. The gas production rate of hydrate regasification was calculated by using the model and the results were basically in agreement with the experimental results. Analysis of disagreement between the experimental and calculated results was made.

关键词

再汽化分解/甲烷水合物/动力学模型

Key words

regasification/ methane hydrate/ kinetic model

分类

能源科技

引用本文复制引用

庞维新,孙福街,李清平,陈光进..甲烷水合物再汽化分解动力学模型建立[J].化工学报,2011,62(7):1906-1914,9.

基金项目

国家高技术研究发展计划项目(2006AA09A209). (2006AA09A209)

化工学报

OA北大核心CSCDCSTPCD

0438-1157

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