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静电纺SF/PEG共混纳米纤维的形态结构与热性能

杜德欢 左保齐 钟天翼

丝绸2011,Vol.48Issue(6):7-11,5.
丝绸2011,Vol.48Issue(6):7-11,5.

静电纺SF/PEG共混纳米纤维的形态结构与热性能

Morphological structure and thermal property of electrospun SF/PLA blend nanofibers

杜德欢 1左保齐 1钟天翼1

作者信息

  • 1. 苏州大学纺织与服装工程学院,江苏苏州215021
  • 折叠

摘要

Abstract

Different ratios of silk fibroin/polyethylene glycol (SF/PEG) blend nanofibers were obtained by electrospinning using Hexafluoroisopropanol(HFIP) as solvent.Morphological structure, molecular structure as well as thermal property of the SF/PEG blend nanofibers were examined using SEM, FT-IR, XRD and DSC analyses.With the increase of PEG content, the average diameters of SF/PEG blend nanofibers decreased from 700 nm to 250 nm.The secondary structure of SF was affected by the addition of low molecular weight PEG.XRD showed that two separate crystalline phases, namely SF and PEG crystalline, existed in the blend nanofibers.Crystal structure of the PEG changed because of the blending, and its phase transition temperature decreased compared with the pure PEG.

关键词

丝素/聚乙二醇纳米纤维/静电纺丝/相变材料/热性能

Key words

SF/PEG nanofibers/ Electrospinning/ Phase change materials/ Thermal property

分类

通用工业技术

引用本文复制引用

杜德欢,左保齐,钟天翼..静电纺SF/PEG共混纳米纤维的形态结构与热性能[J].丝绸,2011,48(6):7-11,5.

基金项目

江苏省高校优势学科一期建设工程项目(苏政办发[2011]6号) (苏政办发[2011]6号)

丝绸

OA北大核心CSTPCD

1001-7003

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