中国计量学院学报2011，Vol.22Issue(2)：185-188,4.
[Ag(PPh3)2(CH3COO)]2·3H2O的合成和晶体结构
Synthesis and crystal structure of [Ag ( PPh3 ) 2 (CH3 COO) ] 23H2O
摘要
Abstract
The complex [Ag(PPh3 )2 (CH43COO)]2 · 3H2O was obtained by the reaction of silver acetate and triphenylphosphine, its structure was characterized by IR, NMR, elemental analysis and single crystal X-ray diffraction. The results of the crystallographic analysis showed that the complex is triclinic, with space group C2/c,a=44. 286 8A,b=13. 269 6A,c=24. 997 0A,a=90. 000°,β= 105. 573°,γ=90. 000°,Z=8,R=0. 052 0,wR2 =0. 132 4.关键词
银配合物/核磁共振/晶体结构Key words
silver complex/ synthesis/ NMR/ single crystal X-ray diffraction分类
化学引用本文复制引用
农平声,黄丽红,周益峰,陈晓红,楼纪东,卢秀莲..[Ag(PPh3)2(CH3COO)]2·3H2O的合成和晶体结构[J].中国计量学院学报,2011,22(2):185-188,4.基金项目
国家教育部留学回国人员资助项目(No.03006-000049),人事部留学回国人员择优资助项目(No.01017-080002),浙江省教育厅资助项目(No.0701206-00003) （No.03006-000049）
