物理化学学报2011，Vol.27Issue(7)：1719-1724,6.
π-共轭三苯基苯衍生物的合成及其胶凝性能
Synthesis of π-Conjugated Triphenylbenzene Derivatives and Their Gelling Property
摘要
Abstract
A series of discotic molecules containing triphenylbenzene group and three monochains were synthesized and their self-assembly properties were studied. These derivatives formed stable gels in many low polarity organic solvents. The lamellar and fibrous aggregate morphologies of the xerogels and the layered structure of the gel aggregates were studied by scanning electron microscopy (SEM) and small angle X-ray diffraction (SA-XRD), respectively. Fourier transform infrared (FT-IR) spectroscopy and UV-Vis absorption spectroscopy revealed that the hydrogen bonding and π-π interactions were the main driving force for the formation of a self-assembled gel. During gel formation, the gelator molecules self-assemble into ordered lamellar aggregates in organic solvents through a π-π conjugation stacking effect and hydrogen bonding. The ordered lamellar aggregates are juxtaposed and interlocked by van der Waals interactions to form sheet-like structure or fiber superstructure and finally immobilize into the organic liquids.关键词
有机凝胶剂/三苯基苯衍生物/自组装/氢键Key words
Organic gelator/ Triphylbenzene deivative/ Self-assembly/ Hydrogen bond分类
化学化工引用本文复制引用
罗序中,王琼,钟金莲,潘虹,陈志兴..π-共轭三苯基苯衍生物的合成及其胶凝性能[J].物理化学学报,2011,27(7):1719-1724,6.基金项目
新世纪优秀人才支持计划(NCET-06-0577),江西省青年科学家培养计划,江西省自然科学基金(2008GZH0012)和江西省研究生创新基金资助项目 （NCET-06-0577）
