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模板法煤沥青基中孔炭的制备及其电化学性能

周颖 宋晓娜 舒成 邱介山

新型炭材料2011,Vol.26Issue(3):187-191,5.
新型炭材料2011,Vol.26Issue(3):187-191,5.

模板法煤沥青基中孔炭的制备及其电化学性能

The electrochemical properties of templated and activated mesoporous carbons produced from coal pitch

周颖 1宋晓娜 1舒成 1邱介山1

作者信息

  • 1. 大连理工大学炭素材料研究室,精细化工国家重点实验室,辽宁大连116024
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摘要

Abstract

Mesoporous carbons ( MCs) were made from coal pitch derived from coal liquefaction residue with silica nanoparticles as template and CO2 as activation agent. The microstructure and electrochemical properties of the MCs were investigated with TEM, N2 adsorption, an electrochemical workstation and a Land battery test system. Results show that the specific surface area increases with activation time at 900 ℃ under a CO2 flow rate of 100 mL·min-1. The specific surface area of MC activated for 150min is 1360 m2·g-1 while that of the un-activated one is 722 m2·g-1. The specific capacitance of the MC activated for 150 min is 135 F·g-1 at a current density of 1 000 mA·g-1 and the decrease in its specific capacitance is 7% after being charged and discharged 10000 times.

关键词

沥青质/模板法/活化/中孔炭/电化学性能

Key words

Coal pitch/ Template method/ Activation/ Mesoporous carbon/ Electrochemical properties

分类

化学化工

引用本文复制引用

周颖,宋晓娜,舒成,邱介山..模板法煤沥青基中孔炭的制备及其电化学性能[J].新型炭材料,2011,26(3):187-191,5.

基金项目

国家自然科学基金(90610003,20725619),国家863项目(2009AA05Z318). (90610003,20725619)

新型炭材料

OA北大核心CSCDCSTPCDSCI

1007-8827

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