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分散剂对MnO_2/AC电化学电容性能的影响

常敬杭 张建民 兰梦 石永伉

电源技术2009,Vol.33Issue(9):777-780,4.
电源技术2009,Vol.33Issue(9):777-780,4.

分散剂对MnO_2/AC电化学电容性能的影响

Influence of dispersant on capacitance performance of manganese dioxide/activated carbon composites

常敬杭 1张建民 1兰梦 1石永伉1

作者信息

  • 1. 郑州大学化学系,河南,郑州,450001
  • 折叠

摘要

Abstract

The amorphous manganese dioxide/activated carbon composites were synthesized with the addition of different series of PEG dispersants by a chem-mixed method. The influence of different dispersants on the performance of MnO_2/AC was studied using X-ray diffraction, constant current charge-discharge, alternate current impendence and cyclic voltammetry. The experimental results show that the polymerization degree of the PEG dispersants has an obvious effect on the electrochemical capacitance performance of MnO_2/AC materials. The electrochemical hybrid supercapacitor was assembled with the PEG400 composite material as the positive electrode and activated carbon as the negative electrode, with a maximum specific capacitance of the composites being 366 F/g in 100 mA/g current density. The capacitance of the capacitor was still kept more than 94% after 500 charge-discharge cycles in 6 mol/L KOH aqueous solutions. The composite materials exhibit good supercapacitance behaviors, such as high reversible characteristics and excellent cycle stability.

关键词

超级电容器/二氧化锰/活性炭/化学混合法

Key words

supercapacitor/ manganese dioxide/activated carbon composites/ chem-mixed method

分类

信息技术与安全科学

引用本文复制引用

常敬杭,张建民,兰梦,石永伉..分散剂对MnO_2/AC电化学电容性能的影响[J].电源技术,2009,33(9):777-780,4.

基金项目

国家自然科学基金资助项目(20873126),郑州市科技攻关项目(083SGYG261 22-1) (20873126)

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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