电源技术2009，Vol.33Issue(9)：781-783,818,4.
不同氧化剂制备的聚苯胺电化学性能研究
Electrochemical performance of polyaniline prepared by different oxidizing agent
摘要
Abstract
Polyaniline was prepared by chemical in-situ polymerization at ambient temperature, using manganese dioxide or ammonium persulphate as oxidant. The morphology and structure of polyaniline were characterized by scanning electron microscopy(SEM), Fourier transform infrared spectroscopy(FTIR) and X-ray diffraction(XRD). The electrochemical performances of the supercapacitor assembled with polyaniline were investigated by cyclic voltammetry, electrochemical impedance spectroscopy and galvanostatic charge-discharge. These results show that the specific capacity of the M-PANI electrode prepared by manganese dioxide was about 260 F/g at the charge-discharge current density of 5 mA/cm~2. After 300 charge-discharge cycles the specific capacity of the M-PANI electrode was about 204 F/g. For comparison, M-PANI has better cycle performance and higher capacity than N-PANI, which was prepared by ammonium persulphate.关键词
聚苯胺/氧化剂/化学氧化聚合法/超级电容器Key words
polyaniline/ oxidant/ chemical in-situ polymerization/ supercapacitor分类
信息技术与安全科学引用本文复制引用
钟新仙,王芳平,李庆余,胡兴艳,卢胜彬,王红强..不同氧化剂制备的聚苯胺电化学性能研究[J].电源技术,2009,33(9):781-783,818,4.基金项目
广西青年科学基金项目(桂科青0832025) （桂科青0832025）
