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SPE水电解池氧电极研究

任丽彬 徐志彬 李勇辉 易炜 张军 刘兴江

电源技术2009,Vol.33Issue(4):326-328,3.
电源技术2009,Vol.33Issue(4):326-328,3.

SPE水电解池氧电极研究

Study on oxygen electrode of SPE water electrolyzer

任丽彬 1徐志彬 1李勇辉 1易炜 1张军 1刘兴江1

作者信息

  • 1. 中国电子科技集团公司,第十八研究所,化学与物理电源技术重点实验室,天津,300381
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摘要

Abstract

Oxygen electrode is a dominant electrode of SPE water electrolyzer (WE), of which diffusion layer and catalyst have direct influence on the performance of WE. The titanium oxygen electrode diffusion layers obtained by thermal decomposition, acid immersion, electro-deposition surface modification were evaluated. The effects of oxygen electrode catalyst, temperature, and oxygen electrode diffusion layer on the performance of WE were also discussed. The results showed that the resistance of Ti oxygen electrode diffusion layer decreased after electro-deposition treatment, and did not increase even if it was exposed to the atmosphere for a long time. IrO2-RuO_2 oxygen electrode catalyst has the best catalytic characteristic. Electrolysis voltage decreased increasing temperature. The WE performance was obviously enhanced when electro-deposited Ti mesh was used as oxygen electrode diffusion layer, its current density was more than 1 A/cm~2 at atmosphere pressure,70 ℃, 1.65 V.

关键词

固体聚合物电解质/水电解/氧电极

Key words

solid polymer electrolyte/ water electrolysis/ oxygen electrode

分类

信息技术与安全科学

引用本文复制引用

任丽彬,徐志彬,李勇辉,易炜,张军,刘兴江..SPE水电解池氧电极研究[J].电源技术,2009,33(4):326-328,3.

电源技术

OA北大核心CSCDCSTPCD

1002-087X

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