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温度对天然焦蒸汽气化特性的影响

向文国 赵长遂 庞克亮

东南大学学报(自然科学版)2009,Vol.39Issue(5):992-997,6.
东南大学学报(自然科学版)2009,Vol.39Issue(5):992-997,6.DOI:10.3969/j.issn.1001-0505.2009.05.025

温度对天然焦蒸汽气化特性的影响

Influence of temperature on natural coke-steam gasification characteristics

向文国 1赵长遂 1庞克亮2

作者信息

  • 1. 东南大学能源与环境学院,南京,210096
  • 2. 国家电站燃烧工程技术研究中心,沈阳,110034
  • 折叠

摘要

Abstract

Steam gasification characteristic of Peicheng natural coke is studied in a bench-scale fluid-ized bed (φ50 mm, 1.6 m). Effects of the operation temperature on the gas yield, carbon conversion, heating value and gas components are discussed. Experimental results are also compared with those of ASPEN PLUS simulation. Experimental results show that gasification temperature is a key parameter. As the temperature goes up, the contents of H_2 and CO_2 in the product gas decline while the content of CO increases. As the gasification temperature rises from 850℃ to 1 000℃, the volume fractions of H_2, CO, and CO_2 in the product gas change from 63. 0% , 25. 0% , and 9. 6% to 59. 8% , 20. 2% , and 18. 5% respectively. Product gas yield increases by 4. 3 times and carbon conversion rate gets increased from 10. 25% to 47. 76% , and the gas heating value increases from 8. 87 to 9. 33 MJ/m~3. The ASPEN PLUS simulation results accord well with the experimental data when the carbon conversion rate is selected according to the experimental results.

关键词

天然焦/流化床/模拟/蒸汽气化/煤气

Key words

natural coke/ fluidized bed/ simulation/ steam gasification/ coal gas

分类

化学化工

引用本文复制引用

向文国,赵长遂,庞克亮..温度对天然焦蒸汽气化特性的影响[J].东南大学学报(自然科学版),2009,39(5):992-997,6.

基金项目

国家自然科学基金资助项目(90410009, 50776018)、国家重点基础研究发展计划(973计划)资助项目(2007CB210101). (90410009, 50776018)

东南大学学报(自然科学版)

OA北大核心CSCDCSTPCD

1001-0505

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